Robust Room-Temperature Polariton Condensation and Lasing in Scalable FAPbBr$_3$ Perovskite Microcavities

TL;DR

This paper demonstrates room-temperature exciton-polariton condensation and lasing in scalable FAPbBr3 perovskite microcavities, showing potential for practical polaritonic devices with efficient fabrication.

Contribution

It introduces a scalable, solution-processed method to achieve room-temperature polariton lasing in FAPbBr3 perovskite microcavities, a rare feat in ambient conditions.

Findings

Polariton lasing observed at room temperature in FAPbBr3 microcavities.

Lasing exhibits lower threshold and longer coherence than photon lasing.

Device remains stable for hours under continuous operation.

Abstract

Exciton-polariton condensation in direct bandgap semiconductors strongly coupled to light enables a broad range of fundamental studies and applications like low-threshold and electrically driven lasing. Yet, materials hosting exciton-polariton condensation in ambient conditions are rare, with fabrication protocols that are often inefficient and non-scalable. Here, room-temperature exciton-polariton condensation and lasing is observed in a microcavity with embedded formamidiniumlead bromide (FAPbBr$_3$) perovskite film. This optically active material is spin-coated onto the microcavity mirror, which makes the whole device scalable up to large lateral sizes. The sub-$\mu$m granulation of the polycrystalline FAPbBr$_3$ film allows for observation of polariton lasing in a single quantum-confined mode of a polaritonic 'quantum dot'. Compared to random photon lasing, observed in bare FAPbBr$_3$ films, polariton lasing exhibits a lower threshold, narrower linewidth, and an order of magnitude longer coherence time. Both polariton and random photon lasing are observed under the conditions of pulsed optical pumping, and persist without significant degradation for up to 6 and 17 hours of a continuous experimental run, respectively. This study demonstrates the excellent potential of the FAPbBr$_3$ perovskite as a new material for room-temperature polaritonics, with the added value of efficient and scalable fabrication offered by the solution-based spin-coating process.