Electronically Amplified Electron-Phonon Interaction and Metal-Insulator Transition in Perovskite Nickelates

TL;DR

This study reveals how electron-phonon interactions, amplified by electronic correlations, drive the metal-insulator transition in perovskite nickelates, highlighting the importance of lattice effects in electronic phase changes.

Contribution

It provides a detailed three-dimensional electronic structure analysis showing the amplification of electron-phonon coupling by correlations during the transition.

Findings

Electron-phonon interaction is amplified in the insulating phase.

Coupling with octahedral phonons affects electron dynamics.

Transition involves transformation from large to small polarons.

Abstract

The relative role of electron-electron and electron-lattice interactions in driving the metal-insulator transition in perovskite nickelates opens a rare window into the non-trivial interplay of the two important degrees of freedom in solids. The most promising solution is to extract the electronic and lattice contributions during the phase transition by performing high-resolution spectroscopy measurements. Here, we present a three-dimensional electronic structure study of Nd1-xSrxNiO3 (x = 0 and 0.175) thin films with unprecedented accuracy, in which the low energy fermiology has a quantitative agreement with model simulations and first-principles calculations. Two characteristic phonons, the octahedral rotational and breathing modes, are illustrated to be coupled with the electron dynamics in the metallic phase, showing a kink structure along the band dispersion, as well as a hump feature in the energy spectrum. Entering the insulating state, the electron-phonon interaction is amplified by strong electron correlations, transforming the mobile large polarons at high temperatures to localized small polarons in the ground state. Moreover, the analysis of quasiparticle residue enables us to establish a transport-spectroscopy correspondence in Nd1-xSrxNiO3 thin films. Our findings demonstrate the essential role of electron-lattice interaction enhanced by the electronic correlation to stabilize the insulating phase in the perovskite nickelates.