High strength self-healable supercapacitor based on supramolecular polymer hydrogel with upper critical solubility temperature

TL;DR

This paper introduces a novel self-healable supramolecular hydrogel-based supercapacitor with high strength, excellent electrochemical performance, and durability, enabled by temperature-responsive hydrogen bonding and innovative electrode materials.

Contribution

The study presents a new self-healable hydrogel with high mechanical strength and electrochemical performance for supercapacitors, utilizing supramolecular polymer chemistry and activated polypyrrole nanotubes.

Findings

Hydrogel exhibits self-healing above upper critical solubility temperature.

Supercapacitor achieves high specific capacitance of 282.62 F g-1.

Device maintains 97% capacitance after 10,000 cycles.

Abstract

Here, we report poly(N-acryloylglycinamide-co-vinyltriazole) p(NAGA-co-VTZ) supramolecular polymer hydrogel doped with activated polypyrrole nanotubes (acPPyNTs) as a high-strength self-healable material for supercapacitors. First, the p(NAGA-co-VTZ) hydrogel films were synthesized by photopolymerization of N-acryloylglycinamide and 1-vinyl-1,2,4-triazole without any cross-linkers. Scanning electron microscopy and mechanical tests showed that initial monomer concentration strongly affects both hydrogel microstructure and resulted mechanical properties. The hydrogels demonstrated self-healing ability through hydrogen bonding at the temperatures above upper critical solubility temperature, excellent mechanical properties (0.9 MPa), large stretchability (1300 %) and cut resistance. Next, as active material for electrochemical double layer capacitors (EDLC) carbonized and ethanol/KOH activated polypyrrole nanotubes (acPPyNTs) were prepared. Symmetric self-healable supercapacitor employing p(NAGA-co-VTZ) hydrogel, acPPyNTs and aqueous 3M KCl solution was assembled. Cyclic voltammetry, galvanostatic charge-discharge measurements showed that the prepared device gave a specific capacitance of 282.62 F g-1 at 0.2 A g-1 and high areal capacitance of 316.86 mF cm-2 at scan rate of 10 mV s-1. The supercapacitor operates over wide voltage window (0-1.2 V) and provides excellent cyclic performance with capacitance retention of 97 % after 10 000 cycles and 94 % after self-healing. Overall, the prepared self-healable supercapacitor appears to have considerable potential as high-performance energy storage device.