Tuning magnetic exchange interactions in 2D magnets: the case of CrGeX$_3$ (X = Se, Te) and Janus Cr$_2$Ge$_2$(Se,Te)$_3$ monolayers

TL;DR

This study computationally investigates how external parameters like strain and electric fields can tune magnetic interactions in 2D van der Waals magnets, revealing phase transitions and emergent interactions with potential multiferroic properties.

Contribution

It provides a detailed analysis of how strain and gate voltage influence magnetic exchange interactions in specific 2D magnets, highlighting mechanisms for phase control and emergent phenomena.

Findings

Strain can induce ferromagnetic to antiferromagnetic phase transitions.

Gate voltage generates Dzyaloshinskii-Moriya interactions and vortex patterns.

Janus monolayers exhibit large electric dipole moments suggesting multiferroic potential.

Abstract

We present a computational study to explore the potential of different experimental approaches to tune the magnetic interactions in two-dimensional van der Waals magnets. We selected CrGeSe$_3$, CrGeTe$_3$, and Janus Cr$_2$Ge$_2$(Se,Te)$_3$ monolayers as case studies and calculated the full exchange tensors among all relevant atomic pairs and analyze their dependence on different external parameters, such as biaxial and uniaxial strain, as well as gate voltage. We pay special attention to interactions that emerge or vanish due to changes of the symmetry of the system. We find that biaxial and uniaxial strains significantly modify isotropic exchange couplings, which can lead to a transition from a ferromagnetic to an antiferromagnetic phase, while a gate voltage induces Dzyaloshinskii-Moriya interactions, forming a vortex pattern whose chirality is determined by the sign of the electric field. The electric dipole moment of the Janus material is large, raising the possibility of multiferroic behaviour. The polarizability is similar for the three compounds.