MX precipitate behavior in an irradiated advanced Fe-9Cr steel: Self-ion irradiation effects on phase stability

TL;DR

This study investigates how self-ion irradiation affects MX-TiC precipitate stability in advanced Fe-9Cr RAFM steel, revealing temperature and damage level dependencies crucial for optimizing radiation-resistant materials for fusion reactors.

Contribution

It provides the first systematic analysis of MX precipitate behavior under irradiation in Fe-9Cr steels, highlighting the roles of temperature and damage level on precipitate stability.

Findings

Pre-existing MX-TiC precipitates coarsen above 400°C at 15 dpa.

Dissolution of precipitates occurs at 50 dpa across all temperatures.

Precipitate stability is influenced by ballistic dissolution and diffusion processes.

Abstract

Reduced activation ferritic/martensitic (RAFM) steels are the leading candidate structural materials for first-wall and blanket components in fusion reactors. This work is the first in a series to provide a systematic roadmap of MX precipitate stability in RAFM steels under various ion irradiation conditions. Here, the MX-TiC precipitate behavior in an advanced Fe-9Cr RAFM steel is assessed under self-ion irradiation to damage levels ranging from 1 to 100 displacements per atom (dpa) at temperatures ranging from 300-600{\deg}C to isolate the effects of temperature and damage level on precipitate stability. The pre-existing MX-TiC precipitates are shown to exhibit temperature-dominated responses, including coarsening above 400{\deg}C at damage levels of 15 dpa, while damage levels studied at 50 dpa and higher showed dissolution across all temperature ranges studied. The effects of ballistic dissolution and diffusion on precipitate behavior are outlined as a function of precipitate characteristics (number density, size, and 25 volume fraction) and irradiation parameters with the use of the recoil resolution model of precipitate stability. This work provides critical insights into MX-TiC stability to high dose in-order to further optimize advanced steels with improved radiation resistance.