The interplay of shape and catalyst distribution in the yield of compressible flow microreactors

TL;DR

This paper presents a semi-analytical model for transport in structured microreactors with compressible fluids, revealing how shape and catalyst distribution influence reactor yield, especially beyond the weakly compressible limit.

Contribution

The study introduces a reduced one-dimensional model incorporating compressibility, shape, and catalyst distribution effects, and experimentally verifies key theoretical predictions.

Findings

Catalyst distribution does not affect yield in weakly compressible reactors.

Inhomogeneous catalyst coatings can enhance yield in strongly compressible reactors.

Reactor shape modifications influence transport and yield beyond the weakly compressible regime.

Abstract

We develop a semi-analytical model for transport in structured catalytic microreactors, where both reactant and product are compressible fluids. Making use of the lubrication and Fick-Jacobs approximations, we reduce the three-dimensional governing equations to an effective one-dimensional set of equations. Our model captures the effect of compressibility, of corrugations in the shape of the reactor, as well as of an inhomogeneous catalytic coating of the reactor walls. We show that in the weakly compressible limit (e.g., liquid-phase reactors), the distribution of catalyst does not influence the reactor yield, which we verify experimentally. Beyond this limit, we show that introducing inhomogeneities in the catalytic coating and corrugations to the reactor walls can improve the yield.