Influence of fluid rheology on multistability in the unstable flow of polymer solutions through pore constriction arrays

TL;DR

This study investigates how fluid rheology affects multistability in elastic flow instabilities of polymer solutions in pore arrays, revealing a key dimensionless parameter that predicts flow behavior.

Contribution

It introduces the streamwise Deborah number as a unifying parameter to predict multistability onset across different polymer solutions and pore geometries.

Findings

Multistability onset correlates with the streamwise Deborah number.

Fluid elasticity and shear-thinning influence flow stability.

Guidelines for designing polymeric fluids with desired flow behaviors.

Abstract

Diverse chemical, energy, environmental, and industrial processes involve the flow of polymer solutions in porous media. The accumulation and dissipation of elastic stresses as the polymers are transported through the tortuous, confined pore space can lead to the development of an elastic flow instability above a threshold flow rate. This flow instability can generate complex flows with strong spatiotemporal fluctuations, despite the low Reynolds number ($\mathrm{Re} \ll 1$); for example, in 1D ordered arrays of pore constrictions, this unstable flow can be multistable, with distinct pores exhibiting distinct unstable flow states. Here, we examine how this multistability is influenced by fluid rheology. Through experiments using diverse polymer solutions having systematic variations in fluid shear-thinning or elasticity, in pore constriction arrays of varying geometries, we show that the onset of multistability can be described using a single dimensionless parameter. This parameter, the streamwise Deborah number, compares the stress relaxation time of the polymer solution to the time required for the fluid to be advected between pore constrictions. Our work thus helps to deepen understanding of the influence of fluid rheology on elastic instabilities, helping to establish guidelines for the rational design of polymeric fluids with desirable flow behaviors.