Crude Oil Displacement Enhanced by Interfacially Active Nanoparticles and Their Coupling Effect with Low-Salinity Brines

TL;DR

This study investigates how interfacially active nanoparticles, specifically pNIPAM, enhance crude oil displacement by altering interfacial properties and how their coupling with low-salinity brines affects oil dewetting dynamics, revealing potential for improved oil recovery.

Contribution

It introduces the use of pNIPAM nanoparticles to improve oil displacement and explores their coupling effects with different low-salinity brines, highlighting new mechanisms for enhanced recovery.

Findings

pNIPAM accelerates oil droplet receding and increases dewetted contact angle

Coupling with divalent CaCl2 slows oil droplet dynamics due to bridging effects

Coupling with monovalent NaCl enhances dewetting and reduces contact angle

Abstract

From the microscopic scale to the petroleum-reservoir scale, the interfacial phenomena of the crude oil-water-rock system crucially control an immiscible flow in a porous reservoir. One of the key mechanisms is crude oil droplet displacement dynamics, which can be optimized by manipulating the oil-water interfacial tension and the three-phase contact angle by means of chemical injection. The current study primarily investigated oil displacement enhanced by interfacially active nanoparticles, namely poly(N-isopropylacrylamide) or pNIPAM, which found an acceleration of oil droplet receding rate (5.66 degree/s) and a greater degree of oil droplet dewetted (37.0 degree contact angle). This was due to a contribution from the nanoparticle-induced structural disjoining pressures between the oil-water and water-solid interfaces. The coupling effect of pNIPAM nanoparticles with low-salinity brines was examined, which revealed a discrepancy in different brine valences. Coupling with divalent CaCl2 led to much slower oil droplet receding dynamics (2.58 degree/s, and 58.7 degree contact angle) since oil-substrate bridging is formulated and promoted by the divalent cation. However, positive synergy was observed with a monovalent NaCl blend. The crude oil dewetting dynamics were enhanced (9.55 degree/s) owing to the combined salt-induced hydration and nanoparticle-induced structural forces. The contact angle was as low as 21.5 degree before eventually detaching from the substrate for a relatively short period (156 s). These findings highlight the coupling effect of nanoparticles and low-salinity brine on the dewetting of heavy crude oil. Adding nanoparticles to an optimal brine could be an option for faster and greater fluid displacement, which is not limited to oil production applications but several others, such as detergency and other forms of geological storage.