Electron transporting bilayers for perovskite solar cells: spray coating deposition of c-TiO2/m-SnO2-quantum dots

TL;DR

This study compares spray-coated mesoporous ETLs of TiO2, SnO2, and SnO2 quantum dots for perovskite solar cells, finding that SnO2 QDs yield the best performance due to their uniform, thin, and compact structure, achieving over 10% efficiency.

Contribution

It introduces a simple spray coating method for depositing SnO2 quantum dot ETLs, demonstrating improved solar cell performance over traditional materials.

Findings

SnO2 QDs ETL results in higher PCE (>10%)

SnO2 QDs form thinner, more uniform layers

Perovskite on SnO2 QDs shows higher PbI2 content

Abstract

Herein we present a comparative study among different mesoporous electron transporter layers (ETLs), namely nanometric m-TiO2, m-SnO2 and m-SnO2 quantum dots (QDs), deposited by spray coating method. The experimental data correlated with the photovoltaic parameters indicate that the SnO2 mesoporous layer obtained from the spray deposition of the in-house prepared QDs solution is the best candidate between the three used mesoporous ETLs. The use of the in-house prepared SnO2 QDs solution presents smaller agglomerates composed of 3 nm NPs resulting in the formation of a thinner, more uniform, and compact mesoporous ETL, compared with the other two ETL solutions. The formamidinium-methylamonium-potassium (FAMA@10K) perovskite deposited on this m-SnO2 QDs ETL presents a lower RMS, more uniformity and, a higher amount of PbI2. Interestingly, this higher concentration for PbI2 seems to enhance the performance of the perovskite solar cells (PSC), compared to the other two mesoporous ETLs. Our work reveals that SnO2 QDs solution can be easily produced in the laboratory and it is more suited for the deposition of the mesoporous ETL when choosing a FAMA@10K configuration perovskite solar cell with power conversion efficiency (PCE) higher than 10%.