Universal Polar Instability In Highly Orthorhombic Perovskites

TL;DR

This paper reveals a universal mechanism in orthorhombic perovskites where coupling of tilt and antipolar modes induces polar distortions, enabling new multiferroic phases with potential for technological applications.

Contribution

It uncovers a universal polar instability driven by invariant couplings in magnetic perovskites, predicting new multiferroic phases with out-of-plane polarization under strain.

Findings

Coupling invariants induce polar distortions in magnetic perovskites.

Epitaxial strain favors the polar $Pna2_1$ phase.

Predicted multiferroics exhibit magnetoelectric properties.

Abstract

The design of novel multiferroic ABO$_3$ perovskites is complicated by the presence of necessary magnetic cations and ubiquitous antiferrodistortive modes, both of which suppress polar distortions. Using first-principles simulations, we observe that the existence of quadlinear and trilinear invariants in the free energy, coupling tilts and antipolar motions of the A and B sites to the polar mode, drives an avalanche-like transition to a non-centrosymmetric $Pna2_1$ symmetry in a wide range of magnetic perovskites with small tolerance factors - overcoming the above restrictions. We find that the $Pna2_1$ phase is especially favoured with tensile epitaxial strain, leading to an unexpected but technologically useful out-of-plane polarization. We use this mechanism to predict various novel multiferroics displaying interesting magnetoelectric properties with small polarization switching barriers.