Designing Strain-less Electrode Materials: Computational Analysis of Volume Variations in Li-ion and Na-ion Batteries

TL;DR

This study uses computational methods to analyze and propose strategies for reducing volume changes in electrode materials, aiming to improve battery durability by designing strain-less electrodes.

Contribution

It introduces a decomposition approach to understand volume variations and suggests material design strategies to control these variations in Li-ion and Na-ion batteries.

Findings

Volume variations can be decomposed into electronic, ionic, and structural contributions.

Chemical substitution and doping can influence each contribution.

Designing mechanically hard or compact materials reduces volume changes.

Abstract

Mechanical degradation in electrode materials during successive electrochemical cycling is critical for battery lifetime and aging properties. A common strategy to mitigate electrode mechanical degradation is to suppress the volume variation induced by Li/Na intercalation/deintercalation, thereby designing strain-less electrodes. In this study, we investigate the electrochemically-induced volume variation in layered and spinel compounds used in Li-ion and Na-ion battery electrode materials through density functional theory computations. Specifically, we propose to decompose the volume variation into electronic, ionic, and structural contributions. Based on this analysis, we suggest methods to separately influence or control each contribution through strategies such as chemical substitution, doping, and polymorphism. Altogether, we conclude that volume variations can be controlled by designing either mechanically hard or compact electrode materials.