Strong-field effects in the photo-induced dissociation of the hydrogen molecule on a silver nanoshell

TL;DR

This paper investigates how strong electromagnetic fields influence the photo-induced dissociation of hydrogen molecules on silver nanoshells, highlighting the importance of considering multiphoton effects in plasmonic catalysis simulations.

Contribution

It demonstrates the significance of strong-field effects and multiphoton absorption in molecular dissociation on plasmonic nanoparticles, challenging the reliance on high-intensity field approximations.

Findings

Hydrogen dissociation occurs via multiphoton absorption and ionization.

Strong-field effects are crucial for accurate interpretation of plasmonic catalysis.

High-intensity fields can lead to different dissociation mechanisms than low-intensity conditions.

Abstract

Plasmonic catalysis is a rapidly growing field of research, both from experimental and computational perspectives. Experimental observations demonstrate an enhanced dissociation rate for molecules in the presence of plasmonic nanoparticles under low-intensity visible light. The hot-carrier transfer from the nanoparticle to the molecule is often claimed as the mechanism for dissociation. However, the charge transfer time scale is on the order of few femtoseconds and cannot be resolved experimentally. In this situation, ab initio non-adiabatic calculations can provide a solution. Such simulations, however, have their own limitations related to the computational cost. To accelerate plasmonic catalysis simulations, many researchers resort to applying high-intensity external fields to nanoparticle-molecule systems. Here, we show why such an approach can be problematic and emphasize the importance of considering strong-field effects when interpreting the results of time-dependent density functional theory simulations of plasmonic catalysis. By studying the hydrogen molecule dissociation on the surface of a silver nanoshell and analyzing the electron transfer at different field frequencies and high intensities, we demonstrate that the molecule dissociates due to multiphoton absorption and subsequent ionization.