All-mirror wavefront division interferometer for mid-infrared spectrometry

TL;DR

This paper introduces an all-mirror wavefront-division interferometer for mid-infrared spectrometry, offering broad spectral coverage, high throughput, and dispersion measurement capabilities, validated through simulations and experiments with supercontinuum sources.

Contribution

The work presents a novel all-mirror interferometer design that is simple, dispersion-free, and suitable for laser-based mid-infrared spectroscopy, expanding spectral range and measurement versatility.

Findings

Successfully demonstrated spectroscopic measurements of polymers and gases.

Achieved broad spectral coverage from 1.5 to 4.4 cm^{-1}.

Validated theoretical model with experimental results.

Abstract

We report on the design of an all-mirror wavefront-division interferometer capable of spectroscopic studies across multiple spectral ranges$\unicode{x2013}$from the plasma frequencies of metals to terahertz wavelengths and beyond. The proposed method leverages the properties of laser sources with high spatial coherence. A theoretical framework for the interferometer scheme is presented, along with an analytical solution for determining the far-field interference pattern, which is validated through both optical propagation simulations and experimental results. The practical implementation of the spectrometer, using cost-effective off-the-shelf components (knife-edge prisms for separation and recombination), is demonstrated. The system features ultra-broad optical bandwidth, high throughput, simple architecture, dispersion-free operation, and variable arm split ratio. These unique attributes make our approach a prospective alternative to standard Fourier transform spectrometer schemes, specifically tailored to laser-based scenarios. Further, the employed design inherently enables the measurement of the sample's dispersion. In the experimental section, we demonstrate the feasibility of spectroscopic measurements by coupling the system with a supercontinuum source with more than an octave-spanning range (1.5 $cm^{-1}$ - 4.4 $cm^{-1}$). As a proof-of-concept, an experimental demonstration is provided for various applied spectroscopic studies: transmission measurements of polymers (polypropylene) and gas (methane), as well as reflectance measurements of dried pharmaceuticals (insulin products on a metal surface).