Parameter-minimal analysis of carbon dioxide removal through direct air capture

TL;DR

This paper applies Chemical Reaction Network Theory to analyze a simplified Earth carbon cycle model with direct air capture, identifying conditions for multiple steady states and providing insights for negative emissions technology assessment.

Contribution

It introduces a parameter-minimal CRNT-based method to analyze multistationarity in Earth system models with direct air capture, aiding in rapid screening of negative emissions technologies.

Findings

Necessary conditions for steady-state multiplicity identified

Insights into system robustness and carbon reduction conditions

Method enables quick screening of negative emissions options

Abstract

The potential for multistationarity, or the existence of steady-state multiplicity, in the Earth System raises concerns that the planet could reach a climatic `tipping point,' rapidly transitioning to a warmer steady-state from which recovery may be practically unattainable. In detailed Earth models that require extensive computation time, it is difficult to make an a priori prediction of the possibility of multistationarity. In this study, we demonstrate Chemical Reaction Network Theory (CRNT) analysis of a simple heuristic box model of the Earth System carbon cycle with the human intervention of Direct Air Capture. CRNT leverages parameter-minimal analysis, relying primarily on the graphical and kinetic structure of the reaction network system, to identify necessary conditions for steady-state multiplicity. The analysis reveals necessary conditions for the combination of system parameters where steady-state multiplicity may exist. With this method, other negative emissions technologies (NET) may be screened in a relatively simple manner to aid in the priority setting by policymakers. Beyond multistationarity, the analysis provides insights into key system properties, such as absolute concentration robustness and some conditions for atmospheric carbon reduction.