Unveiling the Direct Piezoelectric Effect on Piezo-phototronic Coupling in Ferroelectrics: First Principle Study Assisted Experimental Approach

TL;DR

This study investigates how spontaneous and piezoelectric polarization influence piezo-phototronic effects in ferroelectrics, combining experimental and first-principle theoretical approaches to enhance understanding and performance of nanostructured photocatalysts.

Contribution

It provides new insights into the roles of different polarizations in piezo-phototronic coupling and demonstrates the superior flexibility and performance of electrospun nanofibers over sol-gel particles.

Findings

Electrospun nanofibers show 2.5 to 3.75 times higher photocatalytic rate constants.

Nanofibers have a 2.15 times lower elastic modulus, indicating greater flexibility.

Higher piezoelectric strain coefficients in nanofibers improve piezo-phototronic coupling.

Abstract

A new study explores the distinct roles of spontaneous polarization and piezoelectric polarization in piezo-phototronic coupling. This investigation focuses on differences in photocatalytic and piezo-photocatalytic performance using sodium bismuth titanate (NBT), a key ferroelectric material. The research aims to identify which type of polarization has a greater influence on piezo-phototronic effects. A theoretical assessment complements the experimental findings, providing additional insights. This study explores the enhanced piezo-phototronic performance of electrospun nanofibers compared to sol-gel particles under different illumination conditions (11W UV, 250W UV, and natural sunlight). Electrospun nanofibers exhibited a rate constant (k) improvement of 2.5 to 3.75 times, whereas sol-gel particles showed only 1.3 to 1.4 times higher performance when ultrasonication was added to photocatalysis. Analysis using first-principle methods revealed that nanofibers had an elastic modulus (C33) about 2.15 times lower than sol-gel particles, indicating greater flexibility. The elongation of lattice along z-axis in the case of nanofibers reduced the covalency in the Bi-O and Ti-O bonds. These structural differences led to reduced spontaneous polarization and piezoelectric stress coefficients (e31 & e33). Despite having lower piezoelectric stress coefficients, higher flexibility in nanofibers led to a higher piezoelectric strain coefficient, 2.66 and 1.97 times greater than sol-gel particles, respectively. This improved the piezo-phototronic coupling for nanofibers.