Ultrafast spin dynamics: role of laser-induced modification of exchange parameters

TL;DR

This paper investigates how ultrafast laser pulses modify electronic structures and exchange interactions in magnetic materials, revealing significant impacts on spin dynamics and relaxation processes through a combined TD-DFT and Heisenberg model approach.

Contribution

It introduces a two-step scheme combining time-dependent density-functional theory with Heisenberg Hamiltonian calculations to quantify laser-induced changes in exchange parameters.

Findings

Laser pulses cause strong modifications of exchange coupling parameters.

Electronic state repopulation is the main driver of exchange parameter changes.

Modified electronic structures influence spin-lattice interactions during relaxation.

Abstract

Induced by an ultra-short laser pulse, the electronic structure of a material undergoes strong modifications leading to a fast demagnetization in magnetic materials. Induced spin-flip transitions are one of the reasons for demagnetization, that is discussed in the literature as a Stoner-like mechanism. On the other hand, demagnetization due to transverse spin fluctuations is usually discussed on the basis of the Heisenberg Hamiltonian and hardly accounts for the modification of the electronic structure. In this work we demonstrate a strong impact of the laser-induced electron transitions, both spin-flip and spin-conserving, on the exchange coupling parameters. For this, a simple two-step scheme is suggested. As a first step, the electronic structure time evolution during the ultra-short laser pulse is described accurately within time-dependent density-functional theory (TD-DFT) calculations. As a next step, the information on the time-dependent electronic structure is used for calculations of the parameters of the Heisenberg Hamiltonian. A strong modification of the exchange coupling parameters is found in response to the applied ultra-short laser pulse. The most important reason for this modification is played by the laser induced repopulation of the electronic states. Although the changes of the exchange parameters are most prominent during the laser pulse, they may be important also for the magnetic relaxation. The same concerns the spin-lattice interactions playing a central role for the relaxation process. A strong impact of the laser-induced modification of the electronic structure on the spin-lattice coupling parameters is also shown in this work.