Entropic signature of resonant thermal transport: Ordered form of heat conduction

TL;DR

This paper introduces an entropic analysis framework for understanding how nanostructure and boundaries influence thermal transport in crystals, revealing a highly ordered heat conduction regime enabled by phonon resonances that could enable precise phonon control.

Contribution

It presents a novel entropic signature analysis method to characterize the mechanisms of thermal transport in nanostructured materials, highlighting the role of phonon resonances in creating an ordered heat conduction regime.

Findings

Phonon local resonances enable a highly ordered heat conduction regime.

Resonances hinder entropy production and thermal relaxation.

Mode hybridizations caused by resonances promote ordered transport.

Abstract

Thermal transport in crystals is influenced by chemistry, boundaries, and nanostructure. The anharmonic phonon band structure extracted from molecular-dynamics simulations provides an illuminating view of both the type and extent of prevalence of wavelike mechanisms underlying the transport, yet falls short of elucidating the nature of thermal evolution for different phonon regimes. Here we present an analysis framework for the characterization of the entropic signature of the mechanisms induced by boundaries and nanostructure, using both equilibrium and nonequilibrium atomistic simulations. Specifically, we examine the effects of phonon confinement, Bragg scattering, and local resonances on the configurational phase space in room-temperature nanostructured silicon, and quantify how each modifies the rate of entropy production and thermal relaxation. We reveal that the presence of phonon local resonances spanning the full spectrum enables a highly ordered regime of heat conduction to be approached, where irreversible evolution and entropy maximization are severely hindered by extensive mode hybridizations caused by the resonances. This unique regime of transport paves the way for ultra-precise phonon control for a wide range of applications in condensed matter physics.