Impact of Resin Molecular Weight on Drying Kinetics and Sag of Coatings

TL;DR

This study examines how resin molecular weight and solvent evaporation rates influence drying behavior and sag in polymer coatings, revealing that higher molecular weight resins increase diffusivity and reduce sag despite longer drying times.

Contribution

It provides new insights into the effects of resin molecular weight and solvent choice on drying kinetics and sag behavior in coating formulations.

Findings

Higher molecular weight resins increase apparent diffusivity.

Thicker films from higher molecular weight resins dry slower.

Higher molecular weight resins reduce sag velocity due to increased viscosity.

Abstract

The work herein investigates the impact of resin molecular weight and solvent choice on drying kinetics and sag velocity in polymer films. These films, ranging in thickness from ~60 micrometer to ~120 micrometer were formulated with 45% by weight polymer resin in one of two solvent packages with different relative evaporation rates (RER). Gravimetry was initially used to track drying kinetics and a one-dimensional diffusion model was utilized to compute the apparent solvent diffusivity. In addition, the film thickness was tracked with optical profilometry. Results from these measurements showed that for fixed molecular weight the drying kinetics increased by approximately two-fold for the high RER solvent, whereas the apparent diffusivity tended to increase with increasing polymer molecular weight. Films formulated from higher molecular weight resins had greater initial viscosities and thicknesses for identical draw down blade clearance. By extension, the higher apparent diffusivities at greater molecular weights were attributed to effects of prolonged evaporation times for the thicker films. The sag velocity was measured through the thickness of the film for these systems at a 5 degree incline using the Variable Angle Inspection Microscope (VAIM). Measurements showed an increase in sag velocity for thinner and less viscous films, which was somewhat surprising both because a thinner film will experience lower gravitational stress and quicker drying times as compared to a thicker film. From these data we conclude that formulating a coating with higher molecular weight resin, although likely to increase drying time, will tend to deter sag because of the large impact of viscosity on these phenomena.