Electric field dependent thermal conductivity of relaxor ferroelectric PMN-33PT through changes in the phonon spectrum

TL;DR

This study demonstrates that electric fields can significantly modulate the thermal conductivity of relaxor ferroelectric PMN-33PT by altering its phonon spectrum, confirming theoretical predictions and opening pathways for voltage-controlled heat switching.

Contribution

The paper experimentally confirms the theory predicting electric field effects on thermal conductivity in relaxor ferroelectrics, showing larger and opposite effects compared to PZT, and links these effects to piezoelectric properties.

Findings

Thermal conductivity changes up to 11% at room temperature.

Electric field effects are larger and opposite in sign compared to PZT.

Modulation is linked to variations in piezoelectric coefficients.

Abstract

In ferroelectric materials, an electric field has been shown to change the phonon dispersion sufficiently to alter the lattice thermal conductivity, opening the possibility that a heat gradient could drive a polarization flux, and technologically, also opening a pathway towards voltage-driven, all solid-state heat switching. In this report, we confirm the validity of the theory originally developed for Pb(Zr,Ti)O_3 (PZT) on the ferroelectric relaxor 0.67Pb[Mg_(1/3)Nb_(2/3)]O_3-0.33PbTiO_3 (PMN-33PT). In the theory, the change in sound velocity and thermal conductivity with electric field relates to the piezoelectric coefficients and the Gruneisen parameter. It predicts that in PMN-33PT the effect should be an order of magnitude larger, and of opposite sign as in PZT; this is confirmed here experimentally. The effects are measured on samples never poled before and on samples that underwent multiple field sweep cycles and passed through two phase transitions with change in temperature. The thermal conductivity changes are linked to variations in the piezoelectric coefficients and can be as large as 8-11% at room temperature and above. To date, this is the only means of heat conduction modulation that utilizes changes in the phonon spectrum. While this technology is in its infancy, it offers another path to future active thermal conduction control.