Degradation Analysis of Perovskite Solar Cells via Short-Circuit Impedance Spectroscopy: A case study on NiOx passivation

TL;DR

This study uses impedance spectroscopy to analyze degradation mechanisms in NiOx-passivated perovskite solar cells, revealing how interface treatments affect stability and performance, and proposing a method for degradation characterization.

Contribution

It introduces a novel approach using short-circuit impedance spectroscopy to understand and characterize degradation pathways in PSCs with different interface passivations.

Findings

Surface treatments improve device stability.

Protic anion donors initially decrease performance but enhance stability over time.

Capacitance and resistance vary with mobile ion concentration.

Abstract

Perovskite solar cells (PSCs) continue to be the front runner technology among emerging photovoltaic devices in terms of power conversion efficiency and application versatility. However, not only the stability but also the understanding of their ionic-electronic transport mechanisms continues to be challenging. In this work, the case study of NiOx-based inverted PSCs and the effect of different interface passivating treatments on the device performance are approached. Our experiments include impedance spectroscopy (IS) measurements in short-circuit under different illumination intensities and operational stability tests under constant illumination intensity. It is found that certain surface treatments lead to more stable performance. However, protic anion donors can induce, both, an initial performance decrease and a subsequent reactivity during light exposure which apparently improves the cells performance. Our drift-diffusion simulations suggest that the modification of the interface with the hole transport material may have decrease the conductivity, as well as the ion and electron mobilities at the perovskite and the NiOx, respectively. Importantly, capacitance and resistance are shown to peak maximum and minimum values, respectively, around specific ranges of mobile ion concentration. Our results introduce a general route for characterization of degradation paths in PSCs via IS in short-circuit.