Auxetic polymer networks: The role of crosslinking, density and disorder

TL;DR

This paper investigates auxetic behavior in low-connectivity polymer networks, revealing hyper-auxeticity at stability limits and demonstrating that disorder and density significantly influence their mechanical properties, with implications for material science and physics.

Contribution

The study combines simulations and elasticity theory to show hyper-auxeticity in both ordered and disordered polymer networks, highlighting the role of density as a control parameter.

Findings

Diamond-like networks reach the limit of mechanical stability with Poisson's ratio -1.

Disordered networks also exhibit hyper-auxeticity with critical-like behavior.

Density significantly influences the elastic properties of disordered polymer networks.

Abstract

Low-connectivity polymer networks were recently found to behave auxetically when subjected to small tensions, that is, their Poisson's ratio $\nu$ becomes negative. In addition, for specific state points, numerical simulations revealed that diamond-like networks reach the limit of mechanical stability, exhibiting values of $\nu = -1$, a condition that we define hyper-auxeticity. This behavior is interesting per se for its consequences in material science, but also appealing for fundamental physics because the mechanical instability is accompanied by evidences of criticality. In this work, we deepen our understanding of this phenomenon by performing a large set of equilibrium and stress-strain simulations in combination with a phenomenological elasticity theory. The two approaches are found to be in good agreement, confirming the above results. We also extend our investigations to disordered polymer networks and find that the hyper-auxetic behavior also holds in this case, still manifesting a similar critical-like behavior as in the diamond one. Finally, we highlight the role of the number density, that is found to be a relevant control parameter determining the elastic properties of the disordered system. The validity of the results in disordered conditions paves the way to an experimental investigation of this phenomenon in real systems, such as hydrogels.