Superconductivity in Compositionally-Complex Cuprates with the YBa$_2$Cu$_3$O$_{7-x}$ Structure

TL;DR

This study demonstrates high-temperature superconductivity in compositionally complex cuprates with the YBa₂Cu₃O₇₋ₓ structure, showing robustness to disorder and offering a new platform for exploring pairing mechanisms.

Contribution

It introduces compositionally-complex cuprates with the YBa₂Cu₃O₇₋ₓ structure as a robust platform for high-temperature superconductivity research, decoupling spin and lattice disorder.

Findings

T$_C$ exceeds 91 K in all compositions tested.

T$_C$ is only ~1% lower than pure YBCO.

High phase purity and homogeneous mixing confirmed.

Abstract

High-temperature superconductivity is reported in a series of compositionally-complex cuprates with varying degrees of size and spin disorder. Three compositions of Y-site alloyed YBa$_2$Cu$_3$O$_{7-x}$, i.e., (5Y)BCO, were prepared using solid-state methods with different sets of rare earth ions on the Y-site. Synchrotron X-ray diffraction and energy-dispersive X-ray spectroscopy confirm these samples have high phase-purity and homogeneous mixing of the Y-site elements. The superconducting phase transition was probed using electrical resistivity and AC magnetometry measurements, which reveal the transition temperature, T$_C$, is greater than 91 K for all series when near optimal oxygen doping. Importantly, these T$_C$ values are only $\approx$1$\%$ suppressed relative to pure YBCO (T$_C$ = 93 K). This result highlights the robustness of pairing in the YBCO structure to specific types of disorder. In addition, the chemical flexibility of compositionally-complex cuprates allows spin and lattice disorder to be decoupled to a degree not previously possible in high-temperature superconductors. This feature makes compositionally-complex cuprates a uniquely well-suited materials platform for studying proposed pairing interactions in cuprates.