Ferromagnetic response of thin NiI$_2$ flakes up to room temperatures

TL;DR

This study reveals that thin NiI₂ flakes exhibit surface-induced ferromagnetism up to room temperature, contrasting with bulk behavior, and suggests surface effects and degradation influence their magnetic properties.

Contribution

It demonstrates ferromagnetic hysteresis in thin NiI₂ flakes at temperatures above 80 K, highlighting surface effects and the impact of air exposure on magnetic behavior.

Findings

Thin NiI₂ flakes show ferromagnetic hysteresis up to 300 K.

Surface effects cause ferromagnetism independent of sample mass.

Air exposure induces multiferroic-like magnetization modulation.

Abstract

We investigate the magnetic response of thin NiI$_2$ flakes for temperatures above 80~K. Since no magnetic ordering is expected for bulk NiI$_2$, we observe clear paramagnetic response for massive NiI$_2$ single crystals. In contrast, thin NiI$_2$ flakes show well-defined ferromagnetic hysteresis loop within $\pm2$~kOe field range. The value of the response does not scale with the sample mass, ferromagnetic hysteresis can be seen for any flake orientation in the external field, so it originates from the sample surface, possibly, due to the anisotropic exchange (Kitaev interaction). The observed ferromagnetism is weakly sensitive to temperature up to 300~K. If a flake is multiply exposed to air, ferromagnetic hysteresis is accompanied by the periodic modulation of the magnetization curves, which is usually a fingerprint of the multiferroic state. While NiI$_2$ flakes can not be considered as multiferroics above 80~K, surface degradation due to the crystallohydrate formation decreases the symmetry of NiI$_2$ surface, which produces the surface ferroelectric polarization in addition to the described above ferromagnetic one.