Electron-detachment cross sections for O$^-$ + N$_2$ near the free-collision-model velocity threshold

TL;DR

This study measures electron-loss cross sections for O$^-$ ions colliding with N$_2$ molecules between 2.5 and 8.5 keV, explaining previous discrepancies and analyzing velocity dependence near the threshold.

Contribution

It introduces a combined experimental approach and a theoretical model to explain threshold behavior and resolve inconsistencies in low-energy electron-detachment measurements.

Findings

Cross sections show threshold behavior consistent with a free collision model.

Differences between measurement techniques are explained by auto-detaching metastable states.

A simple analytical expression for the velocity threshold is proposed and tested.

Abstract

We present measurements of the total projectile-electron-loss cross sections in O$^-$ + N$_2$ collisions in the energy range from 2.5 to 8.5 keV. Two different techniques, beam attenuation and the growth rate, are employed. The difference between the values obtained with the two methods is explained under the hypothesis of a contribution from anionic metastable auto-detaching states. Under this hypothesis, the long-standing question of a strong disagreement among reported measurements at the low-energy range is also explained. The cross sections measured using the growth-rate method show a threshold behavior. We analyze the cross-section velocity dependence in the framework of a collision between a quasi-free electron, loosely bound to the projectile, and the molecular target. Within the free collision model, we deduce and test a simple analytical expression for the expected velocity threshold taking into account the angular distribution of electron velocities within the anion.