Structural and microscopic relaxations in a colloidal glass

TL;DR

This study investigates microscopic and structural relaxations in a colloidal glass across various time and length scales, revealing a transition from diffusive to hopping dynamics during aging.

Contribution

It provides a comprehensive analysis of relaxation processes in colloidal glasses, combining experimental techniques and simulations to uncover the change in relaxation dynamics across the glass transition.

Findings

Microscopic relaxation remains diffusive with Q^{-2} dependence.

Structural relaxation shifts from Q^{-2} to Q^{-1} dependence during aging.

Both relaxation regimes exhibit stretched correlation functions.

Abstract

The aging dynamics of a colloidal glass has been studied by multiangle Dynamic Light Scattering, Neutron Spin Echo, X-ray Photon Correlation Spectroscopy and Molecular Dynamics simulations. The two relaxation processes, microscopic (fast) and structural (slow), have been investigated in an unprecedentedly wide range of time and length scales covering both ergodic and nonergodic regimes. The microscopic relaxation time remains diffusive at all length scales across the glass transition scaling with wavevector Q as Q^{-2}. The length-scale dependence of structural relaxation time changes from diffusive, characterized by a Q^{-2}-dependence in the early stages of aging, to Q^{-1}- dependence in the full aging regime which marks a discontinuous hopping dynamics. Both regimes are associated with a stretched behaviour of the correlation functions. We expect these findings to provide a general description of both relaxations across the glass transition.