Nanopore-patterned CuSe drives the realization of PbSe-CuSe lateral heterostructure

TL;DR

This paper presents a novel two-step molecular beam epitaxy method to create high-quality monolayer PbSe-CuSe lateral heterostructures with atomically sharp interfaces, enabling exploration of topological quantum phenomena.

Contribution

It introduces a nanopore-patterned CuSe template for lateral epitaxial growth of PbSe, achieving monolayer heterostructures with preserved topological properties.

Findings

Monolayer PbSe-CuSe heterostructure exhibits a 1.8 eV band gap.

Atomically sharp interfaces confirmed by microscopy and spectroscopy.

Weak substrate interaction supported by DFT calculations.

Abstract

Monolayer PbSe has been predicted to be a two-dimensional (2D) topological crystalline insulator (TCI) with crystalline symmetry-protected Dirac-cone-like edge states. Recently, few-layered epitaxial PbSe has been grown on the SrTiO3 substrate successfully, but the corresponding signature of the TCI was only observed for films not thinner than seven monolayers, largely due to interfacial strain. Here, we demonstrate a two-step method based on molecular beam epitaxy for the growth of the PbSe-CuSe lateral heterostructure on the Cu(111) substrate, in which we observe a nanopore patterned CuSe layer that acts as the template for lateral epitaxial growth of PbSe. This further results in a monolayer PbSe-CuSe lateral heterostructure with an atomically sharp interface. Scanning tunneling microscopy and spectroscopy measurements reveal a four-fold symmetric square lattice of such monolayer PbSe with a quasi-particle band gap of 1.8 eV, a value highly comparable with the theoretical value of freestanding PbSe. The weak monolayer-substrate interaction is further supported by both density functional theory (DFT) and projected crystal orbital Hamilton population, with the former predicting the monolayer's anti-bond state to reside below the Fermi level. Our work demonstrates a practical strategy to fabricate a high-quality in-plane heterostructure, involving a monolayer TCI, which is viable for further exploration of the topology-derived quantum physics and phenomena in the monolayer limit.