Strain-Induced Polarization Enhancement in BaTiO$_3$ Core-Shell Nanoparticles

TL;DR

This paper provides a theoretical analysis of how elastic strains and Vegard strains in BaTiO3 core-shell nanoparticles significantly enhance spontaneous polarization, explaining experimental observations of giant polarization values.

Contribution

It introduces a Landau-Ginzburg-Devonshire model considering nonlinear electrostriction and Vegard strains to explain polarization enhancement in ferroelectric core-shell nanoparticles.

Findings

Spontaneous polarization >50 μC/cm² can be stable in 10-100 nm BaTiO3 cores.

Vegard strains and surface stresses further increase polarization up to 100 μC/cm².

Elastic mismatch and electrostriction are key to polarization enhancement.

Abstract

Despite fascinating experimental results, the influence of defects and elastic strains on the physical state of nanosized ferroelectrics is still poorly explored theoretically. One of unresolved theoretical problems is the analytical description of the strongly enhanced spontaneous polarization, piezoelectric response, and dielectric properties of ferroelectric oxide thin films and core-shell nanoparticles induced by elastic strains and stresses. In particular, the 10-nm quasi-spherical BaTiO3 core-shell nanoparticles reveal a giant spontaneous polarization up to 130 mu_C/cm2, where the physical origin is a large Ti off-centering. The available theoretical description cannot explain the giant spontaneous polarization observed in these spherical nanoparticles. This work analyzes polar properties of BaTiO3 core-shell spherical nanoparticles using the Landau-Ginzburg-Devonshire approach, which considers the nonlinear electrostriction coupling and large Vegard strains in the shell. We reveal that a spontaneous polarization greater than 50 mu_C/cm2 can be stable in a (10-100) nm BaTiO3 core at room temperature, where a 5 nm paraelectric shell is stretched by (3-6)% due to Vegard strains, which contribute to the elastic mismatch at the core-shell interface. The polarization value 50 mu_C/cm2 corresponds to high tetragonality ratios (1.02 - 1.04), which is further increased up to 100 mu_C/cm2 by higher Vegard strains and/or intrinsic surface stresses leading to unphysically high tetragonality ratios (1.08 - 1.16). The nonlinear electrostriction coupling and the elastic mismatch at the core-shell interface are key physical factors of the spontaneous polarization enhancement in the core. Doping with the highly-polarized core-shell nanoparticles can be useful in optoelectronics and nonlinear optics, electric field enhancement, reduced switching voltages, catalysis, and electrocaloric nanocoolers.