Perturbation-based Non-perturbative Method
Chang Liu, Wen-Du Li, and Wu-Sheng Dai

TL;DR
This paper introduces a nonperturbative eigenproblem solving method that transforms the problem into a perturbation framework, then analytically continues solutions to obtain accurate results for all energy levels.
Contribution
It proposes a novel approach that combines perturbation theory with analytic continuation to solve eigenproblems nonperturbatively for a wide range of potentials.
Findings
Applicable to almost all potentials
Provides accurate nonperturbative energy approximations
Transforms eigenproblems into perturbation problems for easier solutions
Abstract
This paper presents a nonperturbative method for solving eigenproblems. This method applies to almost all potentials and provides nonperturbative approximations for any energy level. The method converts an eigenproblem into a perturbation problem, obtains perturbation solutions through standard perturbation theory, and then analytically continues the perturbative solution into a nonperturbative solution. Concretely, we follow three main steps: (1) Introduce an auxiliary potential that can be solved exactly and treat the potential to be solved as a perturbation on this auxiliary system. (2) Use perturbation theory to obtain an approximate polynomial of the eigenproblem. (3) Use a rational approximation to analytically continue this approximate polynomial into the nonperturbative region.
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Taxonomy
TopicsAdvanced Physical and Chemical Molecular Interactions · Scientific Research and Discoveries · Advanced Chemical Physics Studies
