Challenges and Opportunities for Second-life Batteries: A Review of Key Technologies and Economy

TL;DR

This review explores technological and economic aspects of second-life lithium-ion batteries, emphasizing degradation modeling, classification standards, profitability, and power electronics to enhance safety and performance in reuse scenarios.

Contribution

It provides a comprehensive analysis of current degradation models, screening techniques, economic viability, and power electronics technologies for second-life batteries, highlighting gaps and future directions.

Findings

Degradation models for first-life batteries can be adapted for SLBs with modifications.

Regrouping standards improve safety and performance of SLBs.

Power electronics significantly enhance SLB efficiency and reliability.

Abstract

Due to the increasing volume of Electric Vehicles in automotive markets and the limited lifetime of onboard lithium-ion batteries (LIBs), the large-scale retirement of LIBs is imminent. The battery packs retired from Electric Vehicles still own 70%-80% of the initial capacity, thus having the potential to be utilized in scenarios with lower energy and power requirements to maximize the value of LIBs. However, spent batteries are commonly less reliable than fresh batteries due to their degraded performance, thereby necessitating a comprehensive assessment from safety and economic perspectives before further utilization. To this end, this paper reviews the key technological and economic aspects of second-life batteries (SLBs). Firstly, we introduce various degradation models for first-life batteries and identify an opportunity to combine physics-based theories with data-driven methods to establish explainable models with physical laws that can be generalized. However, degradation models specifically tailored to SLBs are currently absent. Therefore, we analyze the applicability of existing battery degradation models developed for first-life batteries in SLB applications. Secondly, we investigate fast screening and regrouping techniques and discuss the regrouping standards for the first time to guide the classification procedure and enhance the performance and safety of SLBs. Thirdly, we scrutinize the economic analysis of SLBs and summarize the potentially profitable applications. Finally, we comprehensively examine and compare power electronics technologies that can substantially improve the performance of SLBs, including high-efficiency energy transformation technologies, active equalization technologies, and technologies to improve reliability and safety.