Distinct elastic properties and their origins in glasses and gels

TL;DR

This study reveals fundamental differences in elastic properties and aging behaviors between glasses and gels, linking these differences to their underlying structural mechanisms and providing insights for material design.

Contribution

It uncovers distinct elastic and aging behaviors in glasses and gels, attributing them to structural ordering and interface reduction mechanisms, respectively.

Findings

Glasses show a decreasing shear modulus with constant bulk modulus.

Gels exhibit decreasing shear and bulk moduli over time.

Glasses stiffen steadily during aging, gels initially stiffen then soften.

Abstract

Glasses and gels, widely encountered amorphous solids with diverse industrial and everyday applications, share intriguing similarities such as rigidity without crystalline order and dynamic slowing down during aging. However, the underlying differences between these two fascinating materials have remained elusive. Here we uncover distinct elastic properties concerning observation and aging times in glasses and gels, while delving into the underlying mechanisms. In glasses, we observe a gradual decrease in the shear modulus, while the bulk modulus remains constant throughout the observation time. In contrast, gels exhibit a decrease in both the shear and bulk moduli over the observation time. Additionally, during aging, glasses exhibit a steady trend of stiffening, while gels demonstrate initial stiffening followed by softening. By unravelling the intricate relationship between structure, dynamics, and elasticity, we attribute these differences to mechanisms that minimize free energy: structural ordering in glasses and interface reduction in gels. Our work not only uncovers the distinct behaviors of glasses and gels but also sheds light on the origin and evolution of elasticity in non-equilibrium disordered solids, offering significant implications for the application and design of amorphous materials.