Review on Infrared Nanospectroscopy of Natural 2D Phyllosilicates
Raphaela De Oliveira, Alisson R. Cadore, Raul O. Freitas, Ingrid D., Barcelos

TL;DR
This review discusses the use of infrared scattering-type scanning near-field optical microscopy (IR s-SNOM) to study the nano-optics and chemistry of natural 2D phyllosilicates, highlighting their potential in nanophotonic applications.
Contribution
It provides a comprehensive overview of IR s-SNOM techniques applied to natural 2D phyllosilicates and discusses emerging applications in multifunctional nanophotonic devices.
Findings
IR s-SNOM reveals nano-optical properties of 2D phyllosilicates.
Natural lamellar minerals can be integrated into nanophotonic devices.
Enhanced optical and polaritonic properties observed in 2D heterostructures.
Abstract
Phyllosilicates emerge as a promising class of large bandgap lamellar insulators. Their applications have been explored from fabrication of graphene-based devices to 2D heterostructures based on transition metal dicalcogenides with enhanced optical and polaritonics properties. In this review, we provide an overview on the use of IR s-SNOM for studying nano-optics and local chemistry of a variety of 2D natural phyllosilicates. Finally, we bring a brief update on applications that combine natural lamellar minerals into multifunctional nanophotonic devices driven by electrical control.
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