Honeycomb Layered Frameworks with Metallophilic Bilayers

TL;DR

This review discusses recent advances in honeycomb layered frameworks with metallophilic bilayers, focusing on characterization techniques, new synthesis strategies, and theoretical models relevant to quantum materials.

Contribution

It provides a comprehensive overview of recent experimental and theoretical developments in honeycomb layered frameworks with metallophilic bilayers, emphasizing silver-based oxides and phase transition phenomena.

Findings

Advances in X-ray absorption spectroscopy and HRTEM for characterizing these frameworks.

New strategies for synthesizing cation-deficient phases with bilayer architectures.

Theoretical models describing phase transitions and lattice structures in these materials.

Abstract

This Review highlights the exciting advancements in the science of honeycomb layered frameworks with metallophilic bilayers that have recently garnered attention particularly due to reports of anomalous fractional valency states of silver cations sandwiched between transition metal slabs of other cations. First, the latest tactics and techniques including but not limited to X-ray absorption spectroscopy (XAS) and high-resolution transmission electron microscopy (HRTEM) particularly necessary for characterising recent honeycomb layered frameworks with metallophilic bilayers are described, with emphasis on silver-based oxides. Second, new strategies and concepts related to topochemically- or temperature-induced cationic-deficient phases expanding the compositional space of honeycomb layered frameworks focused on cationic bilayer architectures are also accentuated. Third, the latest condensed matter theoretic advances towards a full, atomistic description of the bilayered structure in such frameworks are detailed, especially related to critical phenomena at the cusp of the monolayer-bilayer phase transition. This entails, in part, describing honeycomb layered frameworks as optimised lattices within the congruent sphere packing problem, equivalent to a particular two-dimensional (2D) conformal field theory. Altogether, it is hoped that this Review will give the reader a panoramic view of the honeycomb layered frameworks with important applications within the emerging field of quantum matter, potentially redefining their frontier. Thus, the scope of this Review is expected to be worthwhile for recent graduates and emerging experts alike not only in the materials science and chemistry community but also in other diverse fields of interest.