High-pressure synthesis and the enhancement of the superconducting properties of FeSe0.5Te0.5

TL;DR

This study demonstrates that high-pressure synthesis significantly enhances the superconducting properties of FeSe0.5Te0.5, including higher transition temperature and critical current density, compared to conventional methods.

Contribution

It introduces a high-pressure synthesis method for FeSe0.5Te0.5 that improves its superconducting properties and microstructure over traditional synthesis techniques.

Findings

Optimal growth conditions (500 MPa, 600°C, 1 h) yield higher Tc and Jc.

Sealing in a Ta-tube improves sample quality.

High-pressure synthesis enhances grain connectivity and pinning properties.

Abstract

A series of FeSe0.5Te0.5 bulk samples have been prepared through the high gas pressure and high-temperature synthesis (HP-HTS) method to optimize the growth conditions, for the first time and investigated for their superconducting properties using structural, microstructure, transport, and magnetic measurements to reach the final conclusions. Ex-situ and in-situ processes are used to prepare bulk samples under a range of growth pressures using Ta-tube and without Tatube. The parent compound synthesized by convenient synthesis method at ambient pressure (CSP) exhibits a superconducting transition temperature of 14.8 K. Our data demonstrate that the prepared FeSe0.5Te0.5 sealed in a Ta-tube is of better quality than the samples without a Ta-tube, and the optimum growth conditions (500 MPa, 600{\deg}C for 1 h) are favourable for the development of the tetragonal FeSe0.5Te0.5 phase. The optimum bulk FeSe0.5Te0.5 depicts a higher transition temperature of 17.3 K and a high critical current density of the order of >10^4 A/cm^2 at 0 T, which is improved over the entire magnetic field range and almost twice higher than the parent compound prepared through CSP. Our studies confirm that the high-pressure synthesis method is a highly efficient way to improve the superconducting transition, grain connectivity, sample density, and also pinning properties of a superconductor.