Non-Gaussian fluctuations of a probe coupled to a Gaussian field
Vincent D\'emery, Andrea Gambassi

TL;DR
This paper investigates the non-Gaussian fluctuations of a probe in a Gaussian field, revealing how kurtosis evolves over time and depends on system parameters, with analytical and numerical validation.
Contribution
It provides an analytical framework for understanding non-Gaussian probe fluctuations in Gaussian fields, extending beyond linear Langevin models.
Findings
Excess kurtosis increases from zero, peaks, then decays algebraically.
Decay exponent depends on spatial dimensionality and field correlations.
Analytical results are validated by numerical simulations.
Abstract
The motion of a colloidal probe in a complex fluid, such as a micellar solution, is usually described by the generalized Langevin equation, which is linear. However, recent numerical simulations and experiments have shown that this linear model fails when the probe is confined, and that the intrinsic dynamics of the probe is actually non-linear. Noting that the kurtosis of the displacement of the probe may reveal the non-linearity of its dynamics also in the absence confinement, we compute it for a probe coupled to a Gaussian field and possibly trapped by a harmonic potential. We show that the excess kurtosis increases from zero at short times, reaches a maximum, and then decays algebraically at long times, with an exponent which depends on the spatial dimensionality and on the features and correlations of the dynamics of the field. Our analytical predictions are confirmed by numerical…
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Taxonomy
TopicsLipid Membrane Structure and Behavior · Spectroscopy and Quantum Chemical Studies · Electrostatics and Colloid Interactions
