Towards reducing tension-compression yield and cyclic asymmetry in pure magnesium and magnesium-aluminum alloy with cerium addition

TL;DR

This study demonstrates that adding cerium to pure magnesium and magnesium-aluminum alloys improves their microstructure, enhances mechanical properties, reduces cyclic asymmetry, and eliminates tension-compression yield differences at room temperature.

Contribution

It reveals how cerium addition refines microstructure and improves mechanical and cyclic properties, especially in pure Mg and Mg-Al alloys, with detailed analysis of underlying mechanisms.

Findings

Cerium addition refines grain size and weakens basal texture in pure Mg.

It eliminates tension-compression yield asymmetry in pure Mg.

Cerium enhances cyclic strength and reduces cyclic asymmetry.

Abstract

In this study, we report the effect of cerium (Ce) addition on the tension-compression yield and cyclic asymmetry in commercially pure magnesium (Cp-Mg) and Mg-Al alloy at room temperature (RT). The investigated materials Cp-Mg, Mg-0.5Ce, and Mg-3Al-0.5Ce were extruded at 400{\deg}C, followed by annealing at the same temperature for one hour. Incorporating 0.5wt.% Ce in pure Mg results in the weakening of its basal texture, uniform distribution of Mg12Ce precipitates, and grain size refinement. Consequently, the tensile yield strength and ductility of pure Mg increased, and tension-compression yield asymmetry was eliminated. However, the presence of 3wt.% Al in Mg suppresses the beneficial effects of Ce addition. The formation of complex precipitates, such as Mg-Al-Ce and Al11Ce3, limits the weakening of the basal texture, reduction in grain size, improvement in ductility, and elimination of tension-compression yield asymmetry observed in Mg-0.5Ce. Nevertheless, Al contributes to the solid solution strengthening in Mg and possibly lowers the critical stress required for twinning in Mg, resulting in the highest tensile strength of Mg-3Al-0.5Ce. Finally, the addition of 0.5wt.% Ce enhances the cyclic strength, stabilizes cyclic stress response, reduces inelastic strain, and minimizes cyclic asymmetry in both pure Mg and Mg-Al alloy while maintaining a comparable fatigue life. Overall, Ce addition positively impacts the microstructure and mechanical behavior of pure Mg and its investigated alloy. The reasons for these improvements are discussed in detail.