An efficient approach to include transport effects in thin coating layers in electrochemo-mechanical models for all-solid-state batteries

TL;DR

This paper introduces a dimensionally reduced, two-dimensional modeling approach for accurately capturing transport effects in thin coating layers of all-solid-state batteries, improving upon zero-dimensional resistance models.

Contribution

The paper presents a novel two-dimensional formulation for coating layers that captures transport phenomena, integrated into a 3D electrochemo-mechanical battery model.

Findings

The new model accurately captures transport effects in coating layers.

It outperforms zero-dimensional resistance models in realistic microstructures.

The approach is validated through conservation, convergence, and comparison tests.

Abstract

A novel approach is presented to efficiently include transport effects in thin active material coating layers of all-solid-state batteries using a dimensionally reduced formulation embedded into a three-dimensionally resolved coupled electrochemo-mechanical continuum model. In the literature, the effect of coating layers is so far captured by additional zero-dimensional resistances to circumvent the need for an extremely fine mesh resolution. However, a zero-dimensional resistance cannot capture transport phenomena along the coating layer, which can become significant, as we will show in this work. Thus, we propose a model which resolves the thin coating layer in a two-dimensional manifold based on model assumptions in the direction of the thickness. This two-dimensional formulation is monolithically coupled with a three-dimensional model representing the other components of a battery cell. The approach is validated by showing conservation properties and convergence and by comparing the results with those computed with a fully resolved model. Results for realistic microstructures of a battery cell, including coating layers as well as design recommendations for a preferred coating layer, are presented. Based on those results, we show that existing modeling approaches feature remarkable errors when transport along the coating layer is significant, whereas the novel approach resolves this.