Structural, vibrational and electronic properties of Nb substituted orthovanadates LaV$_{1-x}$Nb$_x$O$_4$

TL;DR

This study explores how substituting Nb into LaV$_{1-x}$Nb$_x$O$_4$ alters its crystal structure, vibrational modes, and electronic properties, revealing phase transitions and electronic state changes with varying Nb content.

Contribution

It provides a comprehensive analysis of structural, vibrational, and electronic modifications in LaV$_{1-x}$Nb$_x$O$_4$ due to Nb substitution, including phase evolution and electronic state insights.

Findings

Multiple crystal structures identified with Nb doping

New Raman modes associated with Nb bonds appear

Electronic states show systematic changes with Nb content

Abstract

We investigate the structural, vibrational, morphological, and electronic properties of Nb substituted orthovanadate LaV$_{1-x}$Nb$_x$O$_4$ samples prepared by the solid-state reaction method. The x-ray diffraction (XRD) analysis reveals the presence of three crystal structures [monoclinic monazite ($m-m$) type for the $x=$ 0, two-phase equilibrium of monoclinic monazite ($m-m$) and tetragonal scheelite ($t-s$) type for the 0.2$\leq$$x$$\leq$0.8, and monoclinic fergusonite ($m-f$) type for the $x=$ 1 samples] with an increase in Nb$^{5+}$ concentration. The Raman spectroscopy and x-ray photoelectron spectroscopy (XPS) were employed to study the vibrational and electronic properties of all the samples, respectively. In order to choose an excitation wavelength that does not cause undesirable fluorescence and has observable intensities of all the vibrational modes, the Raman spectra are collected using 532 nm, 633 nm, and 785 nm laser lines. With increasing the Nb$^{5+}$ concentration, new Raman modes associated with Nb-bonds are clearly visible and the intensity of V-bonds assigned modes is decreasing. The XPS analysis shows the unchanged 3+ oxidation state of La ion where the intensity of the V 2$p$ core-level decreases while the Nb 3$d$ core-level increases with $x$. The equal spin-orbit energy splitting of the states is confirmed by the average energy difference (across La core-level spectra for all the samples) for state I as well as bonding and anti-bonding of state II. Interesting, the relative intensity of La 3$d$ state I and state II show systematic change with Nb doping altering the metal ligand overlap. We discuss and provide insight into the evolution of the structural, morphological, and chemical features with Nb substitution in LaV$_{1-x}$Nb$_x$O$_4$ samples.