Experimental investigation of solubility trapping in 3D printed micromodels

TL;DR

This study combines experimental and numerical approaches to investigate CO2 bubble trapping and dissolution in 3D printed pore geometries, highlighting challenges in simulation accuracy at low capillary numbers.

Contribution

It provides the first experimental validation of DNS models for complex pore geometries in CO2 trapping and dissolution at the pore scale.

Findings

Experimental results are reproducible and consistent.

DNS models struggle with accuracy due to parasitic currents at low capillary numbers.

Geometrical effects influence CO2 trapping and dissolution behavior.

Abstract

Understanding interfacial mass transfer during dissolution of gas in a liquid is vital for optimising large-scale carbon capture and storage operations. While the dissolution of CO2 bubbles in reservoir brine is a crucial mechanism towards safe CO2 storage, it is a process that occurs at the pore-scale and is not yet fully understood. Direct numerical simulation (DNS) models describing this type of dissolution exist and have been validated with semi-analytical models on simple cases like a rising bubble in a liquid column. However, DNS models have not been experimentally validated for more complicated scenarios such as dissolution of trapped CO2 bubbles in pore geometries where there are few experimental datasets. In this work we present an experimental and numerical study of trapping and dissolution of CO2 bubbles in 3D printed micromodel geometries. We use 3D printing technology to generate three different geometries, a single cavity geometry, a triple cavity geometry and a multiple channel geometry. In order to investigate the repeatability of the trapping and dissolution experimental results, each geometry is printed three times and three identical experiments are performed for each geometry. The experiments are performed at low capillary number representative of flow during CO2 storage applications. DNS simulations are then performed and compared with the experimental results. Our results show experimental reproducibility and consistency in terms of CO2 trapping and the CO2 dissolution process. At such low capillary number, our numerical simulator cannot model the process accurately due to parasitic currents and the strong time step constraints associated with capillary waves. However, we show that, for the single and triple cavity geometry.