# Bistable electric field control of single-atom magnetocrystalline anisotropy

## TL;DR

This paper demonstrates reversible electric field control of a single atom's magnetocrystalline anisotropy by manipulating local electric polarization, enabling atomic-scale magnetic property tuning.

## Contribution

It introduces a method to reversibly switch the magnetic anisotropy of a single atom using electric fields via local polarization changes near a vacancy.

## Key findings

- Electric fields induce bistable polarization changes around vacancies.
- Local polarization modifications alter the magnetocrystalline anisotropy.
- Single-atom magnetic properties can be controlled electrically at the atomic scale.

## Abstract

We reversibly switch the polar environment of an individual magnetic atom with an electric field to control the energy barrier for reversal of magnetization. By applying an electric field in the gap between the tip and sample of a scanning tunneling microscope, we induce bistable changes in the polarization of the region surrounding a chlorine vacancy in a monolayer of sodium chloride on copper terminated by a monolayer of copper nitride. The displacement of the sodium chloride ions alters the local electric polarization and modifies the magnetocrystalline anisotropy experienced by a single cobalt atom. When a cobalt atom is near a chlorine vacancy, spin-sensitive inelastic electron tunneling spectroscopy measurements can reveal the change in anisotropy. The demonstration of atomic-scale control of magnetic properties with electric fields opens new possibilities for probing the origins of magnetoelectric coupling and will stimulate the development of model artificial mutliferroic systems.

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Source: https://tomesphere.com/paper/2302.14667