Study of hydrogen absorption in a novel three-dimensional graphene structure: Towards hydrogen storage applications

TL;DR

This study explores a novel three-dimensional graphene structure that enhances hydrogen absorption capabilities, demonstrating chemisorption of atomic deuterium and potential for improved hydrogen storage applications.

Contribution

It introduces a new 3D graphene architecture that chemisorbs hydrogen atoms via a catalytic splitting mechanism, surpassing limitations of traditional 2D graphene.

Findings

Chemisorption of atomic deuterium on unfunctionalized 3D graphene

Delayed hydrogen desorption due to porous structure

Potential for hydrogen storage applications

Abstract

The use of a novel three-dimensional graphene structure allows circumventing the limitations of the two-dimensional nature of graphene and its application in hydrogen absorption. Here we investigate hydrogen-bonding on monolayer graphene conformally grown via the epitaxial growth method on the (0001) face of a porousified 4H-SiC wafer. Hydrogen absorption is studied via Thermal Desorption Spectroscopy (TDS), exposing the samples to either atomic (D) or molecular (D2) deuterium. The graphene growth temperature, hydrogen exposure temperature, and the morphology of the structure are investigated and related to their effect on hydrogen absorption. The three-dimensional graphene structures chemically bind atomic deuterium when exposed to D2. This is the first report of such an event in unfunctionalized graphene-based materials and implies the presence of a catalytic splitting mechanism. It is further shown that the three-dimensional dendritic structure of the porous material temporarily retains the desorbed molecules and causes delayed emission. The capability of chemisorbing atoms after a catalytic splitting of hydrogen, coupled to its large surface-to-volume ratio, make these structures a promising substrate for hydrogen storage devices.