Momentum-independent magnetic excitation continuum in the honeycomb iridate H$_3$LiIr$_2$O$_6$

TL;DR

This study reveals a broad, momentum-independent magnetic excitation continuum in H$_3$LiIr$_2$O$_6$, supporting its characterization as a disordered topological spin liquid influenced by bond disorder near the Kitaev quantum spin liquid state.

Contribution

It provides experimental evidence of a momentum-independent magnetic continuum in H$_3$LiIr$_2$O$_6$, indicating a disordered topological spin liquid close to the Kitaev limit.

Findings

Broad, momentum-independent magnetic excitation continuum observed.

Continuum consistent with dominant ferromagnetic Kitaev interactions.

Supports the disordered topological spin liquid interpretation.

Abstract

In the search for realizations of Quantum Spin Liquids (QSL), it is essential to understand the interplay between inherent disorder and the correlated fluctuating spin ground state. H$_3$LiIr$_2$O$_6$ is regarded as a spin liquid proximate to the Kitaev-limit (KQSL) in which H zero-point motion and stacking faults are known to be present. Bond disorder has been invoked to account for the existence of unexpected low-energy spin excitations. Controversy remains about the nature of the underlying correlated state and if any KQSL physics survives. Here, we use resonant X-ray spectroscopies to map the collective excitations in H$_3$LiIr$_2$O$_6$ and characterize its magnetic state. We uncover a broad bandwidth and momentum-independent continuum of magnetic excitations at low temperatures that are distinct from the paramagnetic state. The center energy and high-energy tail of the continuum are consistent with expectations for dominant ferromagnetic Kitaev interactions between dynamically fluctuating spins. The absence of a momentum dependence to these excitations indicates a broken translational invariance. Our data support an interpretation of H$_3$LiIr$_2$O$_6$ as a disordered topological spin liquid in close proximity to bond-disordered versions of the KQSL. Our results shed light on how random disorder affects topological magnetic states and have implications for future experimental and theoretical works toward realizing the Kitaev model in condensed matter systems