MgF$_2$ as an effective additive for improving ionic conductivity of ceramic solid electrolytes

TL;DR

This paper introduces MgF$_2$ as an additive that significantly enhances ionic conductivity and stability of NASICON solid electrolytes, enabling more efficient and cost-effective solid-state batteries.

Contribution

The study demonstrates that adding 1 wt% MgF$_2$ to NASICON electrolytes increases ionic conductivity by over 180% and improves stability, offering a new approach for high-performance solid electrolytes.

Findings

Ionic conductivity increased to 2.03 mS/cm at room temperature.

Stability of Na plating/stripping extended from 236 to 654 hours.

MgF$_2$ additive reduces defects in NASICON electrolytes.

Abstract

As typical solid-state electrolytes (SSEs), {Na}$_{1+x}${Zr}$_2${Si}$_{x}${P}$_{3-x}${O}$_{12}$ NASICONs provide an ideal platform for solid-state batteries (SSBs) that display higher safety and accommodate higher energy densities. The critical points for achieving SSBs with higher efficiencies are to improve essentially the ionic conductivity and to reduce largely the interfacial resistance between SSEs and cathode materials, which would necessitate extremely high level of craftsmanship and high-pressure equipment. An alternative to higher-performance and lower-cost SSBs is additive manufacturing. Here, we report on an effective additive, MgF$_2$, which was used in synthesizing NASICONs, resulting in SSEs with fewer defects and higher performance. With an addition of mere 1 wt$\%$ MgF$_2$ additive, the total room-temperature ionic conductivity of the NASICON electrolyte reaches up to 2.03 mS cm$^{-1}$, improved up to $\sim$ 181.3$\%$, with an activation energy of 0.277 eV. Meanwhile, the stability of the Na plating/stripping behavior in symmetric cells increases from 236 to 654 h. We tried to reveal the microscopic origins of the higher ionic conductivity of MgF$_2$-doped NASICONs by comprehensive in-house characterizations. Our study discovers a novel MgF$_2$ additive and provides an efficient way to prepare higher-performance SSEs, making it possible to fabricate lower-cost SSBs in industries.