Cross-sectional profile of photocarrier mobility in thin film solar cell via nongeminate recombination and charge extraction by linearly increasing voltage (cs-p-CELIV)

TL;DR

This paper introduces a novel cross-sectional profiling technique combining p-CELIV with confocal microscopy to measure carrier mobility in thin-film solar cells, providing detailed spatial insights crucial for device optimization.

Contribution

The authors develop a new method, cs-p-CELIV, enabling spatially resolved carrier mobility profiling along the thickness of thin-film photovoltaics, which was previously unavailable.

Findings

The mobility profile correlates with hydrogen content in a-Si:H.

The method accurately maps mobility variations across the solar cell cross section.

Results agree with models emphasizing Si-H bonds' role in mobility.

Abstract

The ability to spatially resolve the carrier mobility profile along the cross section of micrometer-thin solar cells is vital both for fundamental studies in photovoltaics and as a quality control for reproducibly obtaining high conversion efficiencies in commercial solar cell modules. Presently, no technique capable of such an endeavor is available to the best of our knowledge. Here, we introduce a novel method capable of profiling the carrier mobility along the z-axis in thin-film photovoltaics. Our setup is based on the integration of photogenerated charge extraction by linearly increasing voltage (p-CELIV) with a scanning confocal optical microscope (SCOM) towards a cross-sectional sensitive p-CELIV (cs-p-CELIV) system. As geminate recombination of excess carriers is the most frequent radiative pathway for electrons and holes in solar cells at low power density of illumination, while nongeminate recombination dominates at high power, enhanced nongeminate recombination occurs at the SCOM focal plane. Thus, the cs-p-CELIV signal provides enhanced information on the mobility of all of the cross-sectional layers, except for the focal plane. By scanning the focal plane along the z-axis, the mobility profile can be derived. To demonstrate our technique, we use it to investigate the carrier mobility in a hydrogenated amorphous silicon (a-Si:H) solar cell. The mobility profile obtained by cs-p-CELIV correlates well with the H content profile, measured independently, and is in excellent agreement with models suggesting a critical role of Si-H bonding in locally determining the carrier mobility in a-Si:H.