Suppression of the antiferromagnetic order by Zn doping in a possible Kitaev material Na$_2$Co$_2$TeO$_6$

TL;DR

This study systematically investigates how Zn doping suppresses antiferromagnetic order in Na$_2$Co$_2$TeO$_6$, a potential Kitaev material, revealing a transition to a quantum paramagnetic state and providing insights into Kitaev physics.

Contribution

It provides the first detailed phase diagram showing the suppression of magnetic order by Zn doping in Na$_2$Co$_2$TeO$_6$, highlighting the emergence of a quantum paramagnetic state.

Findings

Antiferromagnetic order is suppressed with increasing Zn doping.

A spin-glass phase appears at intermediate doping levels.

High doping levels lead to a magnetically disordered quantum paramagnetic state.

Abstract

Very recently, a 3$d$ based honeycomb cobaltate Na$_2$Co$_2$TeO$_6$ has garnered tremendous attention due to the proposed proximity to the Kitaev spin-liquid state as its 4$d$/5$d$ counterparts. Here, we use Zn to substitute Co in a broad range and perform systematic studies on Na$_2$Co$_{2-x}$Zn$_x$TeO$_6$ by structural, magnetic, and thermodynamic measurements, and track the doping evolution of its magnetic ground states. Due to the extremely close radii of Zn$^{2+}$ and high-spin Co$^{2+}$ ions, the substitution can be easily achieved. X-ray diffractions reveal no structural transition but only minor changes on the lattice parameter $c$ over a wide substitution range $0 \leq x \leq 1.5$. Magnetic susceptibility and specific heat measurements both suggest an antiferromagnetic ground state which is gradually suppressed with doping. It can survive with $x$ up to $\sim1.0$. Then it evolves into a spin-glass phase with short-range order that is rapidly supplanted by a magnetically disordered state when $x \geq 1.3$. By summarizing all these data, we construct a magnetic phase diagram of Na$_2$Co$_{2-x}$Zn$_x$TeO$_6$. Our results demonstrate that the Zn doping can effectively suppress the magnetic order and induce a possibe quantum paramagnetic state. These may serve as a platform to investigate the Kitaev physics in this system.