On the giant deformation and ferroelectricity of guanidinium nitrate

TL;DR

This paper investigates the phase transition-induced giant deformation and ferroelectricity in guanidinium nitrate, addressing previous uncertainties and experimental inconsistencies regarding its ferroelectric and semiconducting properties.

Contribution

The study provides experimental confirmation of ferroelectricity and giant deformation in guanidinium nitrate, clarifying previous conflicting reports and exploring its potential for applications.

Findings

Confirmed ferroelectric properties of GN

Observed giant deformation during phase transition

Addressed defect-related reproducibility issues

Abstract

The extraordinary properties of materials accompanying their phase transitions are exciting from the perspectives of scientific research and new applications. Most recently, Karothu et al.1 described guanidinium nitrate, [C(NH2)3]+[NO3]-, hereafter GN, as a ferroelectric semiconducting organic crystal with exceptional actuating properties. However, the ferroelectric and semiconducting properties of this hybrid organic-inorganic material were not confirmed by the experimental results, and the reproducibility of the large stroke associated with the first-order transition is questionable, because the GN crystals are inherently susceptible to the formation of defects. Besides, previous extensive studies on GN were not acknowledged.