Epitaxial growth, optical and electrical conductivity of the metallic pyrochlore Bi$_2$Ru$_2$O$_7$ on Y-stabilized ZrO$_2$ substrate

TL;DR

This study demonstrates the epitaxial growth and characterization of metallic Bi$_2$Ru$_2$O$_7$ pyrochlore thin films on ZrO$_2$ substrates, revealing their electronic structure, conductivity, and potential anisotropic properties relevant for topological phenomena.

Contribution

First demonstration of epitaxial Bi$_2$Ru$_2$O$_7$ thin films with detailed electronic and optical characterization, highlighting anisotropic properties and potential for topological studies.

Findings

Bi$_2$Ru$_2$O$_7$ is semimetallic with hybridized Ru 4$d$ and Bi 6$p$ orbitals.

Electrical conductivity confirms weak metallic behavior consistent with bulk.

Optical spectra show features indicative of electronic correlations.

Abstract

We report on the epitaxial growth, structural and electrical properties of metallic pyrochlore bismuth ruthenate heterostructures grown along both the [001] and [111] directions. Ordered pyrochlore thin films were obtained with highly oriented texture along the [001] and [111] crystallographic directions. Density functional theory calculations of the electronic band structure and density of states indicated that Bi$_2$Ru$_2$O$_7$ is semimetallic and that hybridization of the Ru 4$d$ and Bi 6$p$ orbitals via the anion network at the Fermi energy was responsible for the metallicity. Electrical conductivity measurements confirmed that the compound is weakly metallic in agreement with the reported conductivity for the stoichiometric bulk compound. The carrier concentration and mobility of the electrons compared favorably with previous reports on bulk material and indicate strong electron-electron interactions. The measured and computed optical conductivities were found to share coincident spectral features and confirm the electronic correlation. Comparison of the electrical and optical properties of the two distinct orientations indicates differences that cannot be attributed to differences in crystalline quality or dislocations and may indicate anisotropy in the electronic structure of Bi$_2$Ru$_2$O$_7$. This study will enable access to the kagome lattice arising naturally in the {111} planes of the pyrochlore B cation sublattice which may be used to uncover emergent topological properties.