Evolution of the reservoirs of volatiles in the protosolar nebula

TL;DR

This study models the evolution of volatile reservoirs in the protosolar nebula, considering all solid phases and their interactions, to explain observed compositional gradients in giant planets.

Contribution

It introduces a comprehensive 1D disk model that includes pure condensates, amorphous ice, and clathrates, advancing understanding of volatile distribution during planet formation.

Findings

Clathrates can crystallize and create enrichment peaks up to ten times initial abundances.

Enrichment peaks of pure condensates form beyond the snowline, reaching about seven times initial abundances.

The initial state of volatiles (pure condensates vs. amorphous ice) significantly affects clathrate formation and volatile distribution.

Abstract

The supersolar abundances of volatiles observed in giant planets suggest that a compositional gradient was present at the time of their formation in the protosolar nebula. To explain this gradient, several studies have investigated the radial transport of trace species and the effect of icelines on the abundance profiles of solids and vapors formed in the disk. However, these models only consider the presence of solids in the forms of pure condensates or amorphous ice during the evolution of the protosolar nebula. They usually neglect the possible crystallization and destabilization of clathrates, along with the resulting interplay between the abundance of water and those of these crystalline forms. This study is aimed at pushing this kind of investigation further by considering all possible solid phases together in the protosolar nebula: pure condensates, amorphous ice, and clathrates. To this end, we used a one-dimensional (1D) protoplanetary disk model coupled with modules describing the evolution of trace species in the vapor phase, as well as the dynamics of dust and pebbles. Eleven key species are considered here, including H$_2$O, CO, CO$_2$, CH$_4$, H$_2$S, N$_2$, NH$_3$, Ar, Kr, Xe, and PH$_3$. Two sets of initial conditions are explored for the protosolar nebula. In a first scenario, the disk is initially filled with icy grains in the forms of pure condensates. In this case, we show that clathrates can crystallize and form enrichment peaks up to about ten times the initial abundances at their crystallization lines. In a second scenario, the volatiles were delivered to the protosolar nebula in the forms of amorphous grains. In this case, the presence of clathrates is not possible because there is no available crystalline water ice in their formation region. Enrichment peaks of pure condensates also form beyond the snowline up to about seven times the initial abundances.