Ion exchange in silicate glass: mass average interdiffusion coefficient determination

TL;DR

This paper introduces a simple method to determine the mass average interdiffusion coefficient in silicate glasses using weight change measurements, enabling better estimation of stress profiles and compression layer depths.

Contribution

A new straightforward technique for calculating the interdiffusion coefficient from weight change data, validated with experimental results on soda-lime silicate glasses.

Findings

The method accurately estimates the interdiffusion coefficient.

The diffusion coefficient follows an Arrhenius temperature dependence.

Estimated compression layer depths agree with optical measurements.

Abstract

The mass average interdiffusion coefficient DM is an approximated constant value of the interdiffusion coefficient which is relevant in the kinetics of ion exchange in silicate glasses. In this study, it is presented a simple technique for its determination based on the weight change of a glass sample after ion exchange. The theoretical basis of the method is presented in detail together with the approximations assumed in considering the constancy of the DM . Experimental results are presented for soda-lime silicate glasses and it is demonstrated the correlation of DM with the ion exchange temperature following an Arrhenius-type equation with an energy activation barrier and a pre-exponential factor. The determination of the mass average interdiffusion coefficient allows the estimation of the compression layer depth when a stress profile is build-up as a consequence of ion exchange. The estimated values of the compression layer depth have been compared with the ones measured by an optical technique based on differential surface refractometry (DSR). Values have been found quite compatible with the uncertainty limits indicated by the DSR method.