IrF4: From Tetrahedral Compass Model to Topological Semimetal

TL;DR

This paper explores how magnetic order influences the topological properties of IrF4, revealing that anisotropic magnetic couplings preserve nodal lines and lead to a novel connection between a compass model and topological semimetals.

Contribution

It introduces a theoretical framework linking the tetrahedral compass model to the topological semimetal phase in IrF4 with magnetic order.

Findings

Magnetic order preserves symmetry-protected nodal lines.

IrF4 exhibits anisotropic magnetic couplings resembling a tetrahedral compass model.

Nodal lines persist into the magnetically ordered phase at the mean-field level.

Abstract

The intersection of topology, symmetry, and magnetism yields a rich structure of possible phases. In this work, we study theoretically the consequences of magnetism on IrF4, which was recently identified as a possible candidate topological nodal chain semimetal in the absence of magnetic order. We show that the spin-orbital nature of the Ir moments gives rise to strongly anisotropic magnetic couplings resembling a tetrahedral compass model on a diamond lattice. The predicted magnetic ground state preserves key symmetries protecting the nodal lines, such that they persist into the ordered phase at the mean-field level. The consequences for other symmetry reductions are also discussed.