Thermal transport properties of the nanocomposite system "porous silicon/ionic liquid"

TL;DR

This study explores the thermal transport in a porous silicon/ionic liquid nanocomposite, revealing significant enhancements in thermal conductivity that could improve thermal management in energy storage devices.

Contribution

It introduces a detailed investigation of thermal properties in a novel porous silicon/ionic liquid nanocomposite system using photoacoustic methods.

Findings

Thermal conductivity more than doubled in porous silicon.

Ionic liquids' thermal conductivity increased over eight times.

Potential applications in thermal management for energy storage.

Abstract

This paper investigates thermal transport in a nanocomposite system "porous silicon matrix filled with ionic liquid". First, the thermal conductivity and heat capacity of two imidazolium and one ammonium ionic liquids were evaluated using the photoacoustic approach in piezoelectric configuration and differential scanning calorimetry, respectively. Then, the thermal transport properties of the composite system "ionic liquid confined inside porous silicon matrix" were investigated with the photoacoustic approach in gas-microphone configuration. It was found that a significant enhancement of the thermal conductivity of the composite when compared to the individual components, i.e. (i) more than two times for pristine porous silicon and (ii) more than eight times for ionic liquids. These results provide new paths for innovative solutions in the field of thermal management in highly efficient energy storage devices.